
The quasichemical model can be used to predict the
thermodynamic properties of multicomponent slags from
the optimized binary and ternary parameters. We are
currently evaluating and optimizing data on all sub-
systems of the SiO2-AI203-CaO-MgO-FeO-MnO-TiO2-
Ti203-ZrO2-Na20-K20- S system.
ACKNOWLEDGMENTS
This work was supported by the Natural Sciences and
Engineering Research Council of Canada. The authors
are indebted to Paul Talley for the ternary graphics and
to Ping Wu for his help with all aspects of the work.
REFERENCES
1. G. Eriksson, P. Wu, M. Blander, and A.D. Pelton: Ecole Poly
technique, Montreal, Canad. Metall. Quart., in press.
2. A.D. Pelton and M. Blander:
Proc. 2ndlnt. Symp. Metall. Slags
and Fluxes,
TMS-AIME, Warrendale, PA, 1984, pp. 281-91.
3. M. Blander and A.D. Pelton:
Proc. 2nd Int. Syrup. Metall. Slags
and Fluxes,
TMS-AIME, Warrendale, PA, 1984, pp. 294-304.
4. A.D. Pelton and M. Blander:
Metall. Trans. B,
1986, vol. 17B,
pp. 805-15.
5. M. Blander and A.D. Pelton:
Geochim. et Cosmochim. Acta,
1987,
vol. 51, pp. 85-95.
6. A.D. Pelton and M. Blander:
Calphad,
1988, vol. 12, pp. 97-108.
7. A.D. Pelton, G. Eriksson, and M. Blander:
Proc. 3rdlnt. Syrup.
Metall. Slags and Fluxes,
The Institute of Metals, London, 1989,
pp. 66-69.
8. A.D. Pelton and G. Eriksson:
Advances in the Fusion of Glass,
Proc. 1st Int. Conf. on Advances in the Fusion of Glass, American
Ceramic Society, Westerville, OH, 1988, pp. 27.1-29.11.
9. A.D. Pelton, W.T. Thompson, C.W. Bale, and G. Eriksson:
Advances in Phase Transitions,
J.D. Embury and G.R. Purdy,
eds., Pergamon Press, New York, NY, 1988, pp. 52-67.
10. A.D.Pelton, G. Eriksson, and M. Blander:
Proc. 4th Int. Symp.
Metall. Slags and Fluxes,
Iron Steel Institute of Japan, Tokyo,
1992, pp. 79-84.
11. M. Blander, A.D. Pelton, and G. Eriksson:
Proc. 4th Int. Symp.
Metall. Slags and Fluxes,
Iron Steel Institute of Japan, Tokyo,
1992, pp. 56-60.
12. P. Wu, G. Eriksson, AD. Pelton, and M. Blander:
J. Iron Steel
Inst. Jpn.,
1993, vol. 33, pp. 25-34.
13. G. Eriksson and A.D. Pelton:
Metall. Trans. B,
1993, vol. 24B,
pp. 795-805.
14. M.L. Kapoor and M.G. Frohberg:
Symp. Chem. Metall. Iron and
Steel,
Sheffield, England, The Institute of Metals, London, 1971.
15. H. Gaye and J. Welfringer:
Proc. 2nd Int. Symp. Metall. Slags
and Fluxes,
TMS-AIME, Warrendale, PA, 1984, pp. 357-76.
16. G.W. Toop and C.S. Samis:
TMS-AIME,
1962, vol. 224, p. 878.
17. P. Wu: Ph.D. Thesis, l~cole Polytechnique, Montr6al, 1992.
18. R.G. Berman, T.H. Brown, and H.J. Greenwood: Report No.
TR-377,
Atomic Energy of Canada Limited,
1985.
19. JANAF Thermochemical Tables, 3rd ed.,
J. Phys. Chem. Ref.
Data,
1985, vol. 14.
20. I. Barin, O. Knacke, and O. Kubaschewski:
Thermochemical
Properties of Inorganic Substances,
Springer-Verlag, Berlin, 1977.
21. I.
Barin: Thermochemical Data of Pure Substances,
VCH,
Weinheim, Germany, 1989.
22. J.F. Elliott and M. Gleiser:
Thermochemistry for Steelmaking,
Addison-Wesley, Reading, MA, 1960.
23. O. Kubaschewski, E.L. Evans, and C.B. Alcock:
Metallurgical
Thermochemistry,
Pergamon, London, 1967.
24. R.G. Berman and T.H. Brown:
Contrib. Mineral Petrol.,
1985,
vol. 89, pp. 168-83.
25. R.G. Berman and T.H. Brown:
Contrib. Mineral. Petrol.,
1986,
vol. 94, p. 262.
26. E.S. Shepherd, G.A. Rankin, and F.E. Wright:
Am. J. Sci., 1909,
vol. 28, pp. 293-333.
27. G.A. Ranldn and F.E. Wright:
Am. J. Sci.,
1915, vol. 39, pp. 1-79.
28. K. Lagerqvist, S.Wallmark, and A. Westgren:
Z. Anorg. Allg.
Chem.,
1937, vol. 234, pp. 1-16.
29. N.E. Filonenko and I.V. Lavrov:
Dokl. Akad. Nauk S.S.S.R.,
1949, vol. 66, pp. 673-76.
30. L.G. Wisnyi: Ph.D. Thesis, Rutgers University, New Brunswick,
New Jersey, 1955.
31. A.L. Gentile and W.R. Foster:
J. Am. Ceram. Soc.,
1963,
vol. 46, pp. 74-76.
32. N.E Filonenko and I.V. Lavrov:
Zh. Priklad. Khim.,
1950,
vol. 23, pp. 1040-46.
33. M. Rolin and H.T. Pham:
Rev. Hautes Temp. R(fractaires,
1965,
vol. 2, pp. 175-85.
34. R.W. Nurse, J.H. Welch, and A.J. Majumdar:
Trans. Br. Ceram.
Soc.,
1965, vol. 64, pp, 323-32.
35. R.W. Nurse, J.H. Welch, and A.J. Majumdar:
Trans. Br. Ceram.
Soc.,
1965, vol. 64, pp. 409-18.
36. N. Nityanand and H.A. Fine:
Metall. Trans. B,
1983, vol. 14B,
pp. 685-92.
37. R.A. Sharma and F.D. Richarson:
J. Iron Steel Inst., London,
1961, vol. 198, pp. 386-90.
38. M. Allibert, C. Chatillon, K.T. Jacob, and R. Lourtau:
J. Am.
Ceram. Soc.,
1981, vol. 64, pp. 307-14.
39. J.P. Coughlin:
J. Am. Chem. Soc.,
1956, vol. 78, pp. 5479-82.
40. O. Kubaschewski and C.B. Alcock:
Metallurgical
Thernzochemistry,
5th ed., Pergamon, N.Y. 1979.
41. E.G. King:
J. Phys. Chem.,
1955. vol. 59, pp. 218-19.
42. B.S. Hemingway:
J. Phys. Chem.,
1982, vol. 82, pp. 2802-03.
43. R.V. Kumar and D.A.R. Kay:
Metall. Trans. B,
1985, vol. 16B,
pp. 107-12.
44. N.L. Bowen and J.W. Greig:
J. Am. Ceram. Soc.,
1924, vol. 7,
pp. 238-54.
45. V. Skola:
Keram. Rundschau,
1937, vol. 45, pp. 188-215.
46. E.C. Shears and W.A. Archibald:
Iron and Steel, London,
1954,
vol. 27, pp. 26-30, 61-66.
47. K. Konopicky:
Bull Soc. Franc. Ceram.,
1956, vol. 33, pp. 33-36.
48. G.Gelsdorf, H. Mueller-Hesse, and H.E. Schwiete:
Arch.
Eisenhiittenw.,
1958, vol. 29, pp. 513-19.
49. N.A. Toropov and F. Ya. Galakhov:
Dokl. Akad. Nauk S.S.S.R.,
1951, vol. 78, pp. 299-302~
50. S. Ararnaki and R. Roy:
J. Am. Ceram. Soc.,
1962, vol. 45,
pp. 229-42.
51. A. Staronka, H. Pham, and M. Rolin:
Rev. Int. Hautes Temp.
R(fract.,
1968, vol. 5, pp. 111-15.
52. S.P. Chaudhuri:
Ceram. Int.,
1987, vol. 13, pp. 167-75.
53. G. Troemel, K.H. Obst, K. Konopicky, H. Baur, and I. Patzsak:
Ber. Deut. Keram. Ges,
1957, vol. 34, pp. 397-402.
54. R.F. Davis and J.A. Pask:
J. Am. Ceram. Soc.,
1972, vol. 55,
pp. 525-31.
55. I.A. Aksay and J.A. Pask:
J. Am. Ceram. Soc.,
1975, vol. 58,
pp. 507-12.
56. F.J. Klug, S. Prochazka, and R.H. Doremus:
J. Am. Ceram.
Soc.,
1987, vol. 70, pp. 750-59.
57. J.F. Schairer and N.L. Bowen:
Am. J. Sci.,
1955, vol. 253,
pp. 681-746.
58. J.F. MacDowell and G.H. Beall:
J. Am. Ceram. Soc.,
1969,
vol. 52, pp. 17-25.
59. C.M. Jantzen, D. Schwahn, J. Schelten, and H. Herman:
Phys.
Chem. Glasses,
1981, vol. 22, pp. 122-37.
60. A. Dhima, B. Stafa, and M. Allibert:
High Temp. Sci.,
1986,
vol. 21, pp. 143-59.
61. H. Schmalzried:
Solid State Reactions,
Academic Press, New York,
NY, 1974, pp. 35-51.
62. J.W. Greig:
Am. J. Sci.,
1927, vol. 13, pp. 1 and 133; vol. 14,
p. 473.
63. G. Troemel, W. Fix, and R. Heinke:
Tonind. Ztg. Keram.
Rundschau,
1969, vol. 93, p. 1.
64. J.D. Tewhey and P.C. Hess:
Phys. Chem. Glasses,
1979, vol. 20,
p. 41.
65. V.B.M. Hageman, G.J.K. van den Berg, H.J. Janssen, and H.A.J.
Oonk:
Phys. Chem Glasses,
1986, vol. 27, p. 100.
66. E.F. Osborn and A. Muan:
Phase Diagrams for Ceramists,
E.M.
Levin, C.R. Robbins, and H.F. McMurdie, eds., The American
Ceramic Society, Columbus, OH, 1964, vol. 1, p. 219.
67. A.L. Gentile and W.R. Foster:
J. Am. Ceram. Soc.,
1963,
vol. 46, p. 76.
68. R.H. Rein and J. Chipman:
TMS-AIME,
1963, vol. 227,
pp. 1193-203.
METALLURGICAL TRANSACTIONS B VOLUME 24B, OCTOBER 1993--815